Imagine a scenario where you get access to remote machine command prompt, and you want to retrieve WiFi Password so that you can connect to WiFi Network and perform your further penetration testing...
Yes, you can enumerate WiFi profiles and retrieve their passwords in Clear Text through windows commands.
Command : "netsh wlan show profiles"
Command : "netsh show profiles samsung key=clear"
These are very small things, But really powerful when you are working on penetration testing assignments, of course this is all scenario based hacking, hope this is helpful.